Experimental and computational diagnosis of the fluxional nature of a benzene-1,3,5-tricarboxamide-based hydrogen-bonded dimer

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چکیده

High-symmetry (left) and low-symmetry (e.g. that on the right) conformations of benzene-1,3,5-tricarboxamide dimers derived from glycine alkyl esters are in rapid exchange solution through amide/ester competition for binding N–H donors.

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ژورنال

عنوان ژورنال: Physical Chemistry Chemical Physics

سال: 2021

ISSN: ['1463-9076', '1463-9084']

DOI: https://doi.org/10.1039/d0cp06128j